<script>
<!--
function getStylesheet() {
var currentTime = new Date().getHours();
if (0 <= currentTime&¤tTime < 5) {
document.write("<link rel='stylesheet' href='night.css' type='text/css'>");
}
if (5 <= currentTime&¤tTime < 11) {
document.write("<link rel='stylesheet' href='morning.css' type='text/css'>");
}
if (11 <= currentTime&¤tTime < 16) {
document.write("<link rel='stylesheet' href='day.css' type='text/css'>");
}
if (16 <= currentTime&¤tTime < 22) {
document.write("<link rel='stylesheet' href='evening.css' type='text/css'>");
}
if (22 <= currentTime&¤tTime <= 24) {
document.write("<link rel='stylesheet' href='night.css' type='text/css'>");
}
}
getStylesheet();
-->
</script>
<noscript><link href="main.css" rel="stylesheet"></noscript>
Name your css files accordingly: night.css, day.css, etc... One cool bonus is that since JavaScript gets the time from the local machine instead of from the server, users will be served the time-based stylesheet based on their time, not the server's, which may be in a completely different timezone.
If JavaScript is disabled in the browser, it will default to the main.css stylesheet.